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AG百家乐有规律吗 青岛大学: DIW打印碳基导电水凝胶, 用于可一稔自供电传感

         发布日期:2024-07-15 04:31    点击次数:106

后果简介AG百家乐有规律吗

跟着健康和东谈主机交互本事的快速发展,用于东谈主体畅通和健康检测的应变传感系统已成为智能健康边界的进犯构成部分。现存的可一稔应变传感器大多依赖外部电源或收场自供电瞬态传感,大大规则了其在可一稔应用中进行及时数据监测的实用性。本文,青岛大学Chenhao Cong、李山东种植、韩国岭南大学Sang Woo Joo等斟酌东谈主员在《ACS Applied Electronic Material》“Bio-Inspired Hydrogen Bonding Cross-Linking Strategy for DIW-Printed Carbon-Based Conductive Hydrogels in Wearable Self-Powered Sensing Systems”的论文,斟酌从自然生物卵白质材料中吸收灵感,诓骗单宁酸(TA)行动纤维素纳米晶体(CNC)、聚乙烯醇(PVA)链和羧化多壁碳纳米管(MWCNT-COOH)之间的分子耦合桥,构建了一个多重氢键系统。多重氢键体系中氢键的动态断裂和邃密导电相聚的造成赋予了水凝胶超卓的性能。

这种步调制备的导电水凝胶具有丰富的里面微结构、优异的导电性(0.47 S/m)、拉伸强度(600%)、机械性能(1.76 MPa)和自规复智商(97%),可在多个边界交叉应用。未经改性的 TA 先行者体溶液具有优异的流变特质,可收场导电水凝胶电极的高精度印刷,以安闲大限制坐褥和纯真定制的应用条款。这些工艺和材料上风的协同作用使三电纳米发电机(TENG)约略网罗畅通能量,并通过应变传感器将其用于东谈主体畅通检测。此外,将这一传感系统与物联网(IoT)本事相麇集,并诓骗5G信号,有助于汉典传输数据,从而收场远距离及时畅通监测。这种概括步调惩办了现存可一稔传感器的局限性,为多样骨子应用场景中的抓续健康监测和东谈主体畅通检测提供了纷乱的惩办决策。

图文导读

图1.自供电应变传感结构和导电水凝胶的多功能特质的默示图。

图 2.(a) PVA/CNC/MWCNT-COOH 先行者体油墨,(b) DIW 印刷油墨默示图,(c,AG真人百家乐靠谱吗d) 物理和化学交联 PVA/CNC/MWCNT-COOH/TA (PCMT) 导电水凝胶的制备历程图。(e) PCMT 导电水凝胶的里面机理图。

图3. (a) Schematic diagram of the principle of DIW printed conductive hydrogel ink. (b) Measurement of PCM20T40 conductive hydrogel electrode under OM for different printing parameters on line width. (c) Physical image of DIW printed conductive hydrogel for printing complex patterns. (d) OM images of different printed line widths by DIW printing parameters. (e) FT-IR spectra of PCM20 and PCM20T40 hydrogels. (f) FTIR spectra of PCM0T40, PCM10T40, PCM20T40, PCM30T40, and PCM40T40 after varying the MWCNT-COOH concentration. Cross-sectional view of SEM images of hydrogel electrodes (g) without and (h) with TA treatment.

图4. (a) Stress–strain curves of conductive hydrogels with different MWCNT-COOH contents. (b) Stretchability of DIW printed PCMT hydrogel electrodes. (c) Adhesion test of PCMT conductive hydrogel on the surface of different substrates. (d) Schematic of the self-healing principle of PCMT conductive hydrogel. (e) Photographs of lit led before and after self-healing of PCMT conductive hydrogel. SEM images of PCMT conductive hydrogel before (f) and after (g) self-healing. (h) Plot of self-healing efficiency versus time after dropping TA solution on the cutoff hydrogel surface. (i) Photographs of the mechanical properties of PCMT hydrogels before and after self-healing.

图5. (a) Variation of tensile resistance of conductive hydrogels at different MWCNT-COOH concentrations. (b) Variation of PCMT conductive hydrogel resistance with increasing strain. (c) Strain response curves of the conductive hydrogel at the same strain level and different strain frequencies. DIW printed wearable strain sensors based on PCMT hydrogel were investigated for detecting the movement of different joints in the human body including (d) fingers, (e) elbows, (f) wrists, (g) anterior side of the knee and (h) posterior side of the knee. Resistance change of (i) conductive hydrogel at 100% elongation over 300 cycles.

图6. (a) Schematic structure of PCMT-TENG. (b) Comparison of the output voltage of PCMT-TENG under different MWCNT-COOH concentrations. (c) Comparison of the output currents of PCMT-TENG under different MWCNT-COOH concentrations. (d) Comparison of output voltages of PCMT-TENG under different contact areas. (e) Comparison of output voltage of PCMT-TENG under different frequencies. (f) Dependence of output voltage and output current of PCMT-TENG on different external load resistors. (g) Dependence of power density of PCMT-TENG on different external load resistors. (h) Charging by commercial capacitors with PCMT-TENG of 0.047, 0.1, and 0.2 μF, respectively (i) continuous charging and discharging with capacitors with PCMT-TENG of 0.47 μF.

图7. (a) Block diagram and operating principle of the integrated sensing system. (b) Self-powered strain sensing system for detecting actual human wrist bending. (c) Schematic of the operation of a self-powered strain sensing system for real-time monitoring of human movement using 5G signal transmission. (d) Real-time response signals of wrist movement are measured by the sensing and displayed on a phone.

小结

在本斟酌中,咱们以冰晶为模板,通过冻融轮回步调开发了一种由 PVA/CNC/MWCNT-COOH/TA 构成的导电水凝胶。随后,咱们基于 DIW 印刷本事并麇集成型步调,制作了可一稔 TENG 和应变传感器的集成系统。该系统旨在通过可一稔、自供电的应变传感系统进步手体畅通识别智商。把柄咱们的斟酌驱逐和斟酌,咱们得出以下论断:

(1) 导电水凝胶的制备:咱们诓骗 TA 行动分子耦合桥与 PVA/CNC/MWCNT-COOH 因素,构建了具有多重氢键系统的导电水凝胶。这些水凝胶发扬出令东谈主称谈的导电性(0.47 S/m)、机械强度(1.76 MPa)、惊东谈主的拉伸性能(600%)和有用的自愈合性能(97%)。

(2) 高精度导电水凝胶电极:诓骗 DIW 印刷本事在柔性基底上制作了高精度导电水凝胶电极,宽度从 150 微米到 600 微米不等。这些电极发扬出冒失的可控性和定制打印复杂图案的智商,这归功于先行者体油墨在 TA 改性前的优异流变特质以及优化的打印和交联过程。

(3) 应变传感器和 TENG:由 PVA/CNC/MWCNT-COOH/TA 导电水凝胶制成的应变传感用具有高智慧度(在 0-600% 拉伸范围内 GF = 0.87)和超强耐用性(在 100% 应变下可承受 300 次拉伸-开释轮回)。TENG 的开路电压为 124 V,短路电流为 18 μA,这归功于以冰晶为模板、MWCNT-COOH/CNC 为骨架结构,通过冻融轮回造成的复杂而邃密的物理相聚结构。

通过将所开发的可一稔应变传感器与 TENGs 相麇集,咱们开发了一个自供电传感系统,该系统可诓骗东谈主体畅通产生的能量对局部要道进行畅通检测。此外,将这种自供电传感系统与物联网本事相麇集,就能收场基于 5G 的数据传输,从而通过个东谈主移动开拓对东谈主体畅通进行及时监测。这项斟酌为探索用于及时东谈主体监测的大限制自供电电子皮肤应用提供了进犯参考。

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